Includes bibliographical references and index.
|Statement||Yury V. Kissin|
|Series||Studies in surface science and catalysis -- v. 173, Studies in surface science and catalysis -- 173.|
|LC Classifications||QD281.P6 K56 2008|
|The Physical Object|
|Pagination||xiv, 592 p. :|
|Number of Pages||592|
|LC Control Number||2010483579|
Alkene Polymerization Reactions with Transition Metal Catalysts - Yury Kissin - Google Books. During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent. The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropyleneThe book provides a detailed description of the multi-center nature of commercial Ziegler-Natta book devotes specialized chapters to the most important aspects of transition metal polymerization catalysts: the reactions leading to the formation of active centers, the chemistry and stereochemistry of elemental polymerization steps, reaction . Summary: During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. Chapter 3 Chemistry and Stereochemistry of Polymerization and Copolymerization Reactions with Transition Metal Catalysts. Yury Kissin. Pages Download PDF. Chapter preview. select article Chapter 4 Synthesis, Chemical Composition, and Structure of Transition Metal Components and Cocatalysts in Catalyst Systems for Alkene Polymerization.
Alkene Polymerization Reactions with Transition Metal Catalysts: Volume by Yury Kissin, , available at Book Depository with free delivery : Yury Kissin. Download Alkene Polymerization Reactions With Transition Metal Catalysts Book For Free in PDF, EPUB. In order to read online Alkene Polymerization Reactions With Transition Metal Catalysts textbook, you need to create a FREE account. Read as many books as you like (Personal use) and Join Over Happy Readers. We cannot guarantee that every book is in the library. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins. The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst . About this book. At the start of the s, Ziegler and Natta discovered that simple metallorganic catalysts are capable of transforming olefins into linear polymers with highly ordered structures. This pioneering discovery was recognized with a Nobel Prize in
The kinetic analysis of transition metal polymerization catalysis is highly developed. Modern experimental techniques for the studies of alkene polymerization kinetics are sophisticated. The book contains an introductory chapter for researchers who are entering the field of polymerization catalysis. It describes the basic principles of polymerization reactions with transition-metal catalysts and the types of commercially manufactured polyolefins and copolymers. After a short introduction on polar organometallic chemistry and synthesis of early main group metal complexes, a variety of catalytic reactions are described, e.g. polymerization of alkenes, hydroamination and phosphination reactions, hydrosilylation, hydroboration and hydrogenation catalysis, as well as enantioselective and Lewis-acid catalysis. The discovery of transition metal catalysts for alkene polymerization by Ziegler 1 and Natta 2 in formed the foundation of today’s polyalkene industry, which in produced over × 10 7 t of polymers. 3 Intense research during this new era of polymer synthesis has resulted in a wide range of highly active and selective catalysts for alkene polymerization. 4–5 Despite such advances, the .